Wow, the VMware community is really great. Thank you all for the responses. It is very much appreciated!
I think that pretty much answers all my questions. VMotion on AD = OK, Snapshots on an AD VM = NO.
This is pretty much confirmed as I have a DC set with drives as Independent / Persistant and it did not give any warnings when going through the migration wizard.
I hadn't planned on using snapshots with AD in the first place due to other posts I had read but was wrongly under the impression that VMotion pretty much did that, hence the post hehe. We use Backup Exec and I do System State backups once a day of all DCs. I wanted to be sure of the VMotion as the most recent DC I virtualized is one of the DCs for the root of the tree and I'm being overly careful due to it!! For the remaining physical DC for the root, I moved all FMSO roles to it and am in the process of confirming that the virtual DC is time syncing correctly.
As a side note, since some were talking about cloning/converting a DC, when P2V'ing the DC in question, I demoted it before the conversion. After getting it up and running in VMware, I promoted it again. Had a few DNS problems which I'm still ironing out but, elsewise, AD seems happy so far. If that DC is the only one for a domain, I'd probably create a temporary second server, promote it, then demote the original and clone.
In case you're interested, as a final and further derailing side note on P2V'ing a DC, I had to open a ticket with VMware to get around a bug with the converter that wouldn't allow for the creation of a vmdk larger than 999GB. There was a 2TB drive on the physical and I had to set the disk size in the converter wizard to minimum. Once it finished, it had errors so I had to reconfigure the VM. After that, I had to use vmkfstools to resize the vmdk and, luckily since it's a Win 2k8 server, I just expanded the partition from the guest OS.
Thanks again to everyone for their help and advice!