Your vm names should have the main IP registered as the vm name, and have the alternate IP addresses as different hostnames. That way, resolution should not be a problem. With all IPs on the same NIC, usually one is used as the main, management IP, and the others are "virtual", in case you needed to run multiple websites, and share the webserver.
As long your vm hostname matches the main IP address, and only one IP address, you should be fine with VCB and NetBackup.
-KjB