You need to configure Identity source in vCenter as mentioned below steps.
1. Login to the vSphere Web Client as administrator@vsphere.local
2. From the home location, navigate to >>Administration >>Single Sign-on >>Configuration and select the Identity Sources tab
3. Click the green + to add an Identity source
4. In the Identity Source page, select Active Directory as a LDAP Server.
5. Fill in the Identity Source Settings information for your Active Directory domain
Name: Label for identification
Base DN for users: The Distinguished Name (DN) of the starting point for directory server searches. Example: If your domain name is domain.internal the DN for the entire directory is "DC=domain, DC=local".
Domain name: Your domain name. Example: "domain.local"
Domain alias: Your netbios name. Example: "XYZ"
Base DN for groups: The Distinguished Name (DN) of the starting point for directory server searches.
Primary server URL: AD Server URL. You can either query the local directory (Port 389), or the global catalog (Port 3268). Example: "ldap://snow.domain.local:3268"
Secondary Server URL: “ldap://rain.domain.local:3268”
Username: A user in the AD Domain with at least browse privileges. Example XZY\vcadmin
6. Click Finish.
7. After clicking Finish, this should add the domain to the list