Greetings,
It appears that you are encountering difficulties while upgrading your hosts from ESXi 6.7 to 7.0. Specifically, you are receiving "Waiting for active nfc sessions to terminate" messages when attempting to enter maintenance mode. Undoubtedly, this can be quite frustrating, especially when striving to complete an upgrade successfully.
VMware employs NFC (Network File Copy) to facilitate the transfer of virtual disks and other files between hosts and storage devices. It is plausible that your backup environment utilizes NFC for transferring backup data, which could be the root cause of the issue you are currently facing. It would be prudent to investigate whether any modifications have been made to your backup environment that could be attributing to this problem.
To address this matter, you can delve into the ESXi logs to identify any errors or warnings associated with NFC or your backup environment. These logs can be accessed by logging in to the ESXi host's console or SSH session and navigating to the /var/log directory. Additionally, it would be beneficial to inspect the vCenter Server logs for any relevant errors or warnings.
Regarding optimizing NFC connections, there are a few settings that can be adjusted to enhance performance. One such parameter is "Net.TcpipHeapSize," which governs the allocation of memory to TCP/IP networking. Increasing this value can potentially improve performance, but it is crucial to exercise caution and avoid setting it too high, as it may result in memory issues. Another parameter that can be adjusted is "Net.VmkLinuxSwapActivitionThreshold," which determines when ESXi will commence swapping memory to disk. Setting this value too low can lead to performance problems.
Pleae Check out these useful resurces:
https://communities.vmware.com/t5/vSphere-Storage-Discussions/ESXI-4-1-Datastore-browser-NFC-error/m-p/314279
https://communities.vmware.com/t5/VMware-vSphere-Discussions/MAX-NFC-connection-buffers-for-network-backup/m-p/2741718
https://communities.vmware.com/t5/Converter-Standalone-Discussions/NFC-connection-fault-during-a-block-level-cloning-operation/m-p/1539736 .... Download
This post will help you to solving your problem.