With CHAP auth it will need to be the same for both targets or you will need to emove the CHAP auth altogether.
Depeding how you define your targets,the easyist would be to define them as additional static tagets for the iscsi intiator.
If the second SANs targets are on other subnet you must config another vmkernel on that subnet and bind it to the iscsi intiator.
Then add the software intiator to the second SAN host access for the luns.
Hope this helps