Your comment "going from ESXi hosts with FCP-attached storage to VxRail (vSAN)" is a little unclear. I'm guessing FCP-attached storage means Fiber correct?
Yes, FCP = Fibre Channel Protocol
so you're saying that as long as the Layer 3 network connectivity is configured correctly I won't need anything else to connect them to the new vCenter?
I take it that even if the IP's are different on these hosts, as long as the network is configured to allow them to communicate with each other then I can do this, did I understand you correctly?
Yes, that's correct. Let me illustrate.
I'm going to move a VM from one FCP-attached datastore across a vCenter and cluster to a totally different array that is also connected via FCP.

The hosts in each cluster have a separate IP schema on separate subnets, but they have L3 connectivity between them.
I initiate a migration, selecting the option to move storage first, from the source side to the destination.
I check the network utilization of the source host's vmnic assigned the management vmkernel port and can clearly see ESXi is moving data over that IP network and not the FCP network.


If I check the destination host which has been selected as the target, I see the inverse happening as it receives the data stream, also over the vmnic assigned management functionality.


Further, if I check the events log for the destination host, I can see the migration is occurring via NFC (Network File Copy) mode but is writing out blocks to the backend datastore.

The operation completes and the VM has been moved to the destination vCenter, cluster, and datastore.
So as long as you have L3 connectivity between management vmkernel ports from source to destination host, the migrations should succeed. Be aware (although it should be obvious enough) that the storage and memory contents (if performed online) will traverse your production network.
EDIT: I should state that the vMotion vmkernel ports for source and destination hosts are in the same broadcast domain, so memory contents traverse that network, but storage data still travels across L3 boundaries over management.