Hello,
Actually, when you have > 1 adapter, you should match the Mac Addresses from seen in vCenter and the VM. Otherwise it could just be guesswork based on the order in which linux adds them to the system which, as previously stated, is based on PCI address and the types of devices in use. When you have more than one of the same device type (E1000, VMXnet, etc) then you need to match your mac address between the two systems. If you use distinct device types then it is easy enough to match without actually looking at vCenter.
Best regards,
Edward L. Haletky
VMware Communities User Moderator, VMware vExpert 2009, 2010, 2011,2012,2013,2014
Author of the books 'VMWare ESX and ESXi in the Enterprise: Planning Deployment Virtualization Servers', Copyright 2011 Pearson Education. 'VMware vSphere and Virtual Infrastructure Security: Securing the Virtual Environment', Copyright 2009 Pearson Education.
Virtualization and Cloud Security Analyst: The Virtualization Practice, LLC -- vSphere Upgrade Saga -- Virtualization Security Round Table Podcast