Both LUNs have unique naa ids. This makes the host think that those actually are different SCSI devices.
One of your LUNs has a runtime name of vmhba40:C0:T0:L4 while the other one has vmhba40:C0:T1:L4, they are behind different targets.
I would first of all check all initiator groups that have the affected host's iqn included and then check the LUN list on NetApp, looking for an 8GB LUN mapped to any of those groups.
If you have VSC integrated with vCenter, you might find it more comfortable for the task above (I would :))
To make sure you're on the right page at some point (i.e. before removing the LUN mapping or the LUN itself, in case you find it neccessary) you might need to compare LUN serial number with NAA ID reported by ESXi.
The only way I've found so far is NetApp CLI: lun serial -x <path to lun>
This returns the LUN hex serial number that in fact matches NAA ID seen by the host. The downside here is that you need to specify a path for each LUN you want to check which might be a considerable effort if you have 100 LUNs to check.
If anyone here knows a better way, please share!
WBR
Imants