>>but how it will install the OS in that Hard Disk that's connected with PVSCSI controller if we are installing it after OS Installation
It seems like you have the boot disk with the pvscsi controller.
The required pvscsi controller will be already there in your initramfs or initrd image which is temporary root file system contains all the necessary drivers like scsi, lvm, raid, etc helps the kernel to mount the actual root file system from the disk which in your case is controlled by pvscsi controller.
# lsinitrd /boot/initramfs-2.6.32-358.el6.x86_64.img | grep -i vmw_pvscsi
-rwxr--r-- 1 root root 41384 Oct 8 23:24 lib/modules/2.6.32-358.el6.x86_64/kernel/drivers/scsi/vmw_pvscsi.ko