Hi,
Let's see:
1. Yes, when you plug in the NIC from ESXi host to the switch it should appear as active.
2. If you have a switch between the host and the NAS that is absolutely normal but you should separate the traffic on VLANs if you don't want to mix your traffic. If you don't care about traffic and it's just for a test, well you could do it without VLANs...
Normally, you allow all VLANs you will use on ESXi's switch ports and then on the vSwitch you tag the VLANs (a.k.a. VST).