Hi,
A VM has a HD (Thin provisioning) of 100GB.
On Windows, 21.6GB are used.
36.11GB is reported in the Web Client
You created a disk of 100 GB so in the VM config, the disk will appear as 100 GB even if only is using 2 GB.
In the Web Client appears the "used storage" for this VM, this includes vmdk files, .swap files, snapshot and so on.
In a second VM there are two HD of 80 and 120GB (Thin Provisioning).
In Windows, 29.5 and 1.5GB are used.
213.13GB is reported in the Web Client
For that one, it's strange that appears as 213 as if you sum both disks it will be 200 GB.
Do you know if there is any snapshot running here?
Another thing you can do is to check the folder inside the VM and see which files are there. This is not truly useful but it can help (VM maybe has LUNs or another storage attached on any other location)