Looks like it can't make out the fstab lines for the main LVM partition:
2012-08-09T10:35:30.879-05:00 [07120 verbose 'Default'] cmdArgs[7]: cd /tmp/.vmware-sysinfo-yugrsrycrgxcbzix/; ./vmware-sysinfo-lin64.sh
2012-08-09T10:35:30.879-05:00 [07120 verbose 'SysCommandWin32'] Starting process: "C:\Program Files (x86)\VMware\VMware vCenter Converter Standalone\plink.exe" "-noprompt" "-stdin" "-P" "22" "-thumbprint" "85:4f:e3:e4:c7:8d:4e:28:3f:51:8b:39:17:d7:34:67" "root@xxx.xxx.xxx" "cd /tmp/.vmware-sysinfo-yugrsrycrgxcbzix/; ./vmware-sysinfo-lin64.sh"
2012-08-09T10:35:32.859-05:00 [07120 info 'Default'] [Converter Agent SysinfoQuery] successfully exec'ed vmware-sysinfo; result: <?xml version="1.0" encoding="UTF-8"?>
--> <sysinfo>
--> <storage>
--> <volume mountPoint="/boot" blockSizeInBytes="1024" capacityInBlocks="495844" blocksFree="402778" blocksUsed="93066" devicePath="/dev/sda1" fileSystemType="ext4" isBootVolume="true" label=""/>
--> <disk type="msdos" controllerType="scsi" bus="3" deviceId="0" capacityInSectors="156301488">
--> <device path="/dev/sda" major="8" minor="0"/>
--> <hwGeometry cylinders="9729" heads="255" sectors="63"/>
--> <biosGeometry cylinders="9729" heads="255" sectors="63"/>
--> <partition number="1" type="primary" isActive="true" fileSystemType="ext3">
--> <device path="/dev/sda1" major="8" minor="1"/>
--> <lba start="2048" length="1024000" end="1026047"/>
--> </partition>
--> <partition number="2" type="primary" isActive="false" fileSystemType="">
--> <device path="/dev/sda2" major="8" minor="2"/>
--> <lba start="1026048" length="155275264" end="156301311"/>
--> </partition>
--> </disk>
--> <volumeGroup version="2" name="vg_cleveland" capacityInBytes="79498838016" freeSpaceInBytes="0"/>
--> </storage>
--> <network>
--> <interface label="eth0" nicId="xx:xx:xx:xx:xx:xx" status="up">
--> <ip address="xx.xx.xx.xx" mask="xx.xx.xx.xx"/>
--> </interface>
--> </network>
--> <operatingSystem>
--> <hostname>xxx.xxx.xxx</hostname>
--> <distribution name="rhel" version="6.3 (Santiago)"/>
--> <kernel release="2.6.32-279.2.1.el6.x86_64" is64bit="true" SMP="false"/>
--> </operatingSystem>
--> <hardwareInfo>
--> <firmwareType>bios</firmwareType>
--> <cpuCount>4</cpuCount>
--> <coresCount id="0">4</coresCount>
--> <memoryInKb>3801088</memoryInKb>
--> </hardwareInfo>
--> <grub>
--> <devicemap>
--> <device biosNumber="0" path="/dev/sda"/>
--> </devicemap>
--> </grub>
--> </sysinfo>
-->
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] Invoking C:\Program Files (x86)\VMware\VMware vCenter Converter Standalone\plink.exe with the following arguments:
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[0]: -noprompt
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[1]: -stdin
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[2]: -P
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[3]: 22
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[4]: -thumbprint
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[5]: 85:4f:e3:e4:c7:8d:4e:28:3f:51:8b:39:17:d7:34:67
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[6]: root@xxx.xxx.xxx
2012-08-09T10:35:32.859-05:00 [07120 verbose 'Default'] cmdArgs[7]: cat /tmp/.vmware-sysinfo-yugrsrycrgxcbzix/vmware-sysinfo.log
2012-08-09T10:35:32.859-05:00 [07120 verbose 'SysCommandWin32'] Starting process: "C:\Program Files (x86)\VMware\VMware vCenter Converter Standalone\plink.exe" "-noprompt" "-stdin" "-P" "22" "-thumbprint" "85:4f:e3:e4:c7:8d:4e:28:3f:51:8b:39:17:d7:34:67" "root@xxx.xxx.xxx" "cat /tmp/.vmware-sysinfo-yugrsrycrgxcbzix/vmware-sysinfo.log"
2012-08-09T10:35:33.723-05:00 [07120 verbose 'Default'] Converter Agent SysinfoQuery grabbed log file; result: [2012-08-09 10:35:31,157 INFO storage ]: Probing for disks using parted
--> [2012-08-09 10:35:31,158 INFO storage ]: Parted returned device with path: /dev/sda, type: 1
--> [2012-08-09 10:35:31,170 INFO storage ]: Parted successfully probed device with path: /dev/sda, type: 1, disk type: msdos
--> [2012-08-09 10:35:31,170 INFO storage.disk ]: Creating SCSI disk with path: /dev/sda
--> [2012-08-09 10:35:31,295 INFO storage ]: LVM2 executables found
--> [2012-08-09 10:35:31,731 WARN storage.lvm ]: Failed to match lvs output line ' lv_root|vg_cleveland|73324822528B|-wi-ao--|1
--> '.
--> [2012-08-09 10:35:31,731 WARN storage.lvm ]: Failed to match lvs output line ' lv_swap|vg_cleveland|6174015488B|-wi-ao--|1
--> '.
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: /dev/mapper/vg_cleveland-lv_root, dir: /, type: ext4
--> [2012-08-09 10:35:31,732 INFO storage ]: Looking for device with major 253 and minor 0
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: proc, dir: /proc, type: proc
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: sysfs, dir: /sys, type: sysfs
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: devpts, dir: /dev/pts, type: devpts
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: tmpfs, dir: /dev/shm, type: tmpfs
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: /dev/sda1, dir: /boot, type: ext4
--> [2012-08-09 10:35:31,732 INFO storage ]: Looking for device with major 8 and minor 1
--> [2012-08-09 10:35:31,732 INFO storage ]: Found device /dev/sda1
--> [2012-08-09 10:35:31,732 WARN storage.volume ]: Creating volume with mountPoint: /boot, device path: /dev/sda1, fsType: ext4, _blockSizeInBytes: 1024, _capacityInBlocks: 495844, _blocksFree: 402778
--> [2012-08-09 10:35:31,732 INFO storage.volume ]: Device /dev/sda1 is not a FAT volume
--> [2012-08-09 10:35:31,732 WARN storage.volume ]: Unrecognized file system on device /dev/sda1, label will not be preserved
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: none, dir: /proc/sys/fs/binfmt_misc, type: binfmt_misc
--> [2012-08-09 10:35:31,732 INFO storage ]: Got mount table entry: fsname: sunrpc, dir: /var/lib/nfs/rpc_pipefs, type: rpc_pipefs
--> [2012-08-09 10:35:31,732 INFO storage ]: Getting stats for swap device /dev/dm-1
--> [2012-08-09 10:35:31,732 INFO storage ]: Swap device /dev/dm-1 has block device number (major,minor): (253,1)
--> [2012-08-09 10:35:31,734 WARN network ]: Ignoring interface 'lo' because it is not an ethernet interface
--> [2012-08-09 10:35:31,734 INFO distribution ]: /etc/redhat-release file line: 'Red Hat Enterprise Linux Server release 6.3 (Santiago)'
--> [2012-08-09 10:35:31,751 INFO hardwareInfo ]: /proc/sys/kernel/bootloader_type has valie: '113'
--> [2012-08-09 10:35:31,752 INFO grub ]: Trying to create device map file /tmp/vmware-sysinfo-grub-device.map
--> [2012-08-09 10:35:31,752 INFO grub ]: Running command: grub --batch --no-floppy --device-map=/tmp/vmware-sysinfo-grub-device.map > /dev/null 2>&1
--> [2012-08-09 10:35:32,325 INFO sysinfo ]: <?xml version="1.0" encoding="UTF-8"?>
I think the OS is a relatively "vanilla" install onto the 80GB disk so I'm surprised to see this. How would this be resolved?