Is it possible to put a DS into maintenance mode? This will just evacuate the DS.
Can the network on each host be paused or disconnected while keeping VMs powered up? can disconnect , this will cause issue and outages
I have been in this situation and because of this kind of activity finally end up with fixing lot of read-only VMs, recovering etc..
This need to evaluate carefully
what type of outage the network team expect ? do they bring a new switch and cut-over to that one
What storage you have ? is it nfs ? VSAN is sensitive to network .. so get the complete picture and figure out what is happening during maintenance activity and what is the impact