Thanks for your reply.
I'm aware of the MVMC and have actually installed it on one of our servers. But was of that impression (told by an employee who has been here longer than me, I just started), that they have tried this many times, and that seems outdated.
But I have now tested with this tool, but get an authentication error when I try to connect to the ESXi host/cluster (I did try both).
I'm not sure why, because I use the exact same credentials to access the vCenter server from a browser, and seems to have full administrative rights with this account.
So I'm a little stuck with this tool so far.
On the other hand, is it not possible to export VMs directly from ESXi?