I'm not sure what you mean by "cannot be fragmented or expanded", because to reclaim an unused place is just the opposite: Compact. You can do defragmentation, too, which may or may not be helping to Compact.
If you have a Snapshot (not sure what your screenshots are showing or not showing), then you can NOT reclaim space. The reason is that if there is a Snapshot, then nothing is ever deleted, but just marked as deleted. In this case, you have to remove first ALL Snapshots in order to reclaim space.