Hello Manuel,
"The main doubt is: is this officially supported? I haven't found any statement regarding"
Not to be a buzzkill, but it is literally the first thing mentioned in that article:
"Disclaimer: The technology tested here is not currently supported by VMware and may never be. This is not recommended for use in any production environment, especially where VMware support is required.."
"and also I have some doubt about the durability of a NVME drive for cache, because the spare space (all the space over the 600GB limit)"
How NVMe/SSDs have as high TBW as they do is by using ALL of the device over time via dynamic wear-levelling (+ the extra % that is hidden from the user assigned only for this purpose).
Using Cache-tier devices far larger than 600GB isn't that uncommon for the above reason - a good example being VMConAWS nodes (which accounts for likely thousands of nodes) using 1.8TB NVMe as Cache-tier.
While the article you have referenced is a cool example of what is theoretically possible, I would think it more likely that changes to how much of a single device Cache-tier vSAN can actively use being a more feasible option (as this doesn't rely on non-VMware protocols and potentially vendor-specific implementations of nvme namespaces etc.).
Bob