Hello suhag79
If all nodes are on 6.6 build of ESXi/vSAN and have disks on latest on-disk format as they do appear to have in your screenshot then Unicast as the mode of communication is expected.
You can easily verify the network communication and connectivity between vSAN nodes in a number of ways:
From the Health UI in the vSphere Web Client:
Cluster > Monitor > Health > Network drop-down - if these are green for the main tests then network is likely fine.
From the CLI via SSH:
Check the Cluster membership includes all nodes:
# esxcli vsan cluster get
Check that their Unicast lists are fully populated with all other nodes in the clusters info:
# esxcli vsan unicastagent list
Check ping between the vmk configured on one host to the others e.g.:
# vmkping -I vmkX 192.168.X.X
(get the IP and vmk# of the vSAN interface from GUI or #esxcfg-vmknic -l)
You can also check that creation of VMs/Objects that are FTT=1 (Default Storage Policy) is possible by manually creating a VM or using the VM creation test under proactive tests - this would not be possible without network connectivity between enough hosts to satisfy the placement requirements of the SP (3 nodes/FDs).
Bob