Hello Chris,
Not sure of the PowerCLI cmdlet, but to take the ESXi host to maintenance mode while specifying an action the VSAN service must take before the host can enter maintenance mode (default noAction) you may try the below command:
esxcli system maintenanceMode set -e true -m ["ensureObjectAccessibility" or "evacuateAllData" or "noAction"]
NOTE: These options exist for ESXi 6.0.