sorry I missed the license info in your initial post...
So first if you have a two separate SSO domains "Connect to a remote site" is the correct option exactly as it is on your screen shot.
Next step is to type correctly IP/FQDN of the server on the target site where PSC is running...for successful registration with target PSC
you need credentials of the DR site SSO domain user who has priviledge assigned (i.e. -> VRM administrator User Role).
The last but not least step is to verify that traffic between ESXi host (its VR agent) on primary site to VR Appliance at DR site is routed properly ...
By default vSphere Replication is using ESXi management interface to send replication traffic to the VReplication appliance on the DR site. (its also possible to separate VR traffic from mgmt network)
Please post hbrsrv.log and hms.log
In addition to the HBR ports you need also:
Default Port | Protocol or Description | Source | Target | Endpoints or Consumers |
80 | TCP | vSphere Replication appliance | Remote vCenter Server | All management traffic to the vSphere Replication appliance goes to port 80 on the vCenter Server proxy system. |
80 | HTTP | vSphere Replication appliance | Remote ESXi host | Used to establish the connection before initial replication starts |