Ok, I should have been more precise. It was there (sort of) but it wasn't really usable :smileywink:
Some remarks:
1) It's important to know the difference between vmstores: (all connected vcenters) and vmstore: (the last connected vcenter)
2) If you have folders in the root of your vcenter or between your datacenter and the datastore(s), they have to be included in the path
3) The path elements are case-sensitive. Although the vSphere client apparently is not (try creating a 'folder' and a 'Folder' for example)
4) Use the Copy-DatastoreItem cmdlet (instead of Copy-Item) when the source and/or the destination is a datastore
Would you care to elaborate on the "still not ready for general purpose" ?
Why do the release notes mention "Files cannot be copied in or out the Datastore Provider" under Datastore Provider in the Known Issues ?