Yes, there is nothing to stop an ESXi host participating in both a VSAN cluster, and also accessing other storage over supported protocols such as NFS, FC, FCoE or iSCSI.
However, you will not be able to use the LUNs or Volumes presented over NFS, FC, FCoE or iSCSI for VSAN storage.
VSAN requires local disks to build the VSAN datastore.
I guess the only concern would be the additional management overhead that comes with having lots of different storage types, but this is true even if VSAN wasn't in the picture.