Hi Paul,
There are a few different questions there, hopefully I can answer all.
It is not common to have an in sync replication setup between Greenplums like you might have with NAS storage systems. Greenplum does not have an automatic replicating system.
As per the documentation there are 2 methods used. The most common method we see is the backup and restore.
pgbouncer is used more for leaving connections open. In a busy system alot of time can be spend opening and closing connections to the DB, pgbouncer allows the user to have a constant connection without having to hold it from the users side.
You can have more than one backup cluster, but it would mean you have to restore to each cluster every time to remain in sync.
Does this answer everything? If no let me know.
Regards,
Peter