Siva,
I would make sure to set BOTH of these settings to port 25, it is the standard port for email communication and will make life easier in the long run.
RequestProcessor.ServerSocketPort = 25
RequestProcessor.MTAResubmitPort = 25
Also the issue might be a TLS issue..
You may want to disable the TLS connection string:
RequestProcessor.AllowExtensions - Remove the STARTTLS string at the end of the setting.
Also make sure that the proofpoint server is ALLOWING connections from the DLP server IP, sometimes it is configured to ONLY accept connections from the Exchnage server for security.
Once you have made the change, recycle the DLP Server Services.
Then try to connect to the EMAIL PREVENT SERVER via telnet on Port 25, you should get a hello from the Proofpoint server.
Good Luck,
Ronak
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