Hello Samir,
I understand that you believe the MBR on your system is corrupt. However, I would like some clarification before you move further.
What are the symptoms here?
Are you certain that the MBR is corrupt, and it's not just the bootguard?
If you are able to get to bootguard, and enter your passphrase, then get an error message, I agree, your MBR is probably corrupt. In this case, you should certainly decrypt the drive before doing any additional troubleshooting. Symantec Encryption Desktop (PGP Desktop) does not have any feature to automatically fix your MBR, so decryption would be neccesary before troubleshooting the MBR.
However, if you do not see bootguard, the issue may be that the bootguard pre-boot data has become corrupt. There is a bootg.iso file, which will search your drive for the bootguard recovery information, which is written to a random spot on the disk for events like this. The bootg.iso disc will find and attempt to restore the bootguard, and you may be able to log in as normal if that is the only problem. If bootg.iso fixes the problem, and you are able to login, I recommend backing up your data immediately.
In either case, all of our standard recovery procedures for encryption desktop are available via this link,
Drive Encryption Diagnosis and Recovery - Symantec Drive Encryption & PGP Whole Disk Encryption - http://www.symantec.com/docs/TECH149679