ok so I would create a new simple block DS and run all the VM's through converter, that way you know they are safe.
Then I would check the VASA provider registration in VC;
vCenter level, Configure, Storage Providers.... I'm guessing that your VASA provider is either missing or the certificate has expired.
For either of the above issues please check with your array vendor on how best to proceed...
But your priority should be to copy the VM's to stable block storage first; Converter will help you do that... if the VM's power off they may disappear...
Good luck
Fouad