VMotion won't necessarily trigger any VAAI operations. All VMotion really does is move the executing location of a VM from server to server.
Storage VMotion between datastores on LUNs on the same supported storage controller should use the Full Copy VAAI primitive which uses the SCSI EXTENDED COPY command under the covers. vCenter VM cloning will also use Full Copy.
Creating an eagerzerothick VMDK should use the Block Zeroing primitive which calls SCSI WRITE SAME.
Creating/deleting files, adding blocks to files (by writing enough data to it to grow to the next VMFS block size or some multiple of the block size), adding a server to a cluster, starting/stopping a VM and a few other operations should trigger Hardware-Assisted Locking which calls SCSI COMPARE AND WRITE.
Not sure about EMC, but on NetApp there are counters you can use to actually see this happening.