What is your goal? A 2 TB LUN? If so, why not just create a 2 TB Raid Group.
vCenter does not get assigned LUNS, you assign them to all of the hosts. So if you create 4 500GB LUNs, you would assign them to all of the hosts that will share the data.
I would think MS OS raid config would work if you really wanted to do that, but my question is why?
-Matt
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