Please post screenshots of the VMKernel port configuration for each iSCSI port. Make sure that the iSCSI1 port has vmnic3 as it's primary, and vmnic2 as not used. iSCSI2 port should then have vmnic2 as primary, and vmnic3 as not used.
It appears they are direct connected. Make sure there is NO way that one of the ports on either end of the cable are set to gigabit half-duplex (before I get flamed, Gb half duplex IS REAL, it's mainly for hubs and repeaters, but it's real, and it's in the spec). I've seen this happen once ever, but check it to make sure.
If the connection is passing through a switch, please let us know what kind of switch, and how many "hops" the connection is taking to get from host to the PowerVault array