The steps I have followed to move ESXi from old vcenter to New vCenter.
1)If you have redundant NICs to pass the traffic, please remove one vmnic and add that NIC to standard switch.
#Migrating vmnic from vDS to vSS
$vmhost | Get-VirtualSwitch -name $vss_name | Add-VirtualSwitchPhysicalNetworkAdapter -VMHostPhysicalNic $vmnic1 -Confirm:$false
2)Create pg on standard switch and migrate the VMs from vDS to standard switch
#Adding new vSS
Get-VirtualSwitch -VMHost $vmhost -Name vSwitch1 | New-VirtualPortGroup -Name vmpg_100 -VLanId 100
#Migrating management network
$mgmt_name = "Management_vLAN208"
$mgmt_vmk = Get-VMHostNetworkAdapter -VMHost $vmhost -Name "vmk0"
$mgmt_pg = New-VirtualPortGroup -VirtualSwitch $vss -Name $mgmt_name -VLanId 208
$vmhost | Get-VirtualSwitch -name $vss_name | Add-VirtualSwitchPhysicalNetworkAdapter -VMHostPhysicalNic $vmnic3 -VMHostVirtualNic $mgmt_vmk -VirtualNicPortgroup $mgmt_pg -Confirm:$false
# migration/edit of VM port group VDS to VSS
Get-vmhost $vmhost | Get-VM |Get-NetworkAdapter |Where {$_.NetworkName -eq $Oldpg_100} |Set-NetworkAdapter -NetworkName $Newpg_100 -Confirm:$false
3)Remove redundant vmnic on vDS and then remove vDS switch attached to the ESXi host
#After checking no VMs on any port groups please remove redundant NICs
$vmhost | Get-VirtualSwitch -name $vss_name | Add-VirtualSwitchPhysicalNetworkAdapter -VMHostPhysicalNic $vmnic2 -Confirm:$false
4)Disconnect the host in old vCenter and add it back the host in New vCenter.
Set-VMHost -VMHost $vmhost -state Disconnected
5)Attach the distributed switch to the ESXi host in New vcenter and add only one vmnic
$gz_vds = Get-VDSwitch "dvSwitch-MCOM-Ops2-V5-GreenZone"
$gz_vds | Add-VDSwitchVMHost -VMHost $vmhost
#migrating vSS to vDS vmnic0
$gz_vmhostNetworkAdapter = get-vmhost -Name $vmhost | Get-VMHostNetworkAdapter -Physical -Name vmnic0
$gz_vds | Add-VDSwitchPhysicalNetworkAdapter -VMHostNetworkAdapter $gz_vmhostNetworkAdapter
6)Move VMs to new vCenter vDS and once the migration is done, delete the vmnic in vSS and add back to vDS.
Get-vmhost $vmhost | Get-VM |Get-NetworkAdapter |Where {$_.NetworkName -eq $Oldpg_100} |Set-NetworkAdapter -NetworkName $Newpg_100 -Confirm:$false