The following gives you the NTFS permissions on the files in the SSL folder.
It assumes that the admiistrative share C$ is there, and that the account under which you execute the script has access to that share.
An alternative would be to use the Invoke-VMSCript cmdlet, provided the vCenter is a VM.
Another alternative is to use PowerShell remoting, but that requires WinRM to be configured.
$vCenter = $global:DefaultVIServer.Name
$acl = Get-ChildItem "\\$($vCenter)\c$\ProgramData\VMware\VMware VirtualCenter\SSL" -recurse | Get-Acl
foreach($file in $acl){
$file.Access |
Select @{N="File";E={$file.PSChildName}},
@{N="Path";E={$file.Path.Split(':')[2]}},
@{N="Owner";E={$file.Owner}},
@{N="Name";E={$_.IdentityReference}},
@{N="Type";E={$_.AccessControlType}},
@{N="Rights";E={$_.FileSystemRights}}
}