Although the LUN size is limited to 2TB - 512 bytes, the VMFS and datastore volume size limit is much greater. The maximum volume size is 64TB - 16KB. This can be accomplished by leveraging the maximum extents (32) per volume.
If you require a single datastore that is larger than 2TB - 512 bytes in size, you may want to add extents so that the datastore resides on multiple LUNs of 2 TB - 512 bytes or less.
You really need 1 volume with 2TB + ? You cant create two volumes of ~2TB, multiextend may not is a best solutions, but if you need it. Go ahead.