Nice catch! I missed that.
With the path corrected I still get the "Unable to create virtual disk with specified parameters" message but now VMware vSphere Clients reports "A specified parameter was not correct. spec.device"
This is what I'm entering.
vmkfstools.pl --server ???.???.???.??? --username root --password ?????? -r /vmfs/devices/disks/vml.0100000000395653343158564b314532443131303041393033393635305345 /vmfs/volumes/1TB-SATA/3ware9650se-rdm.vmdk -a lsilogic