You are assumptions are correct in regards to setting up the Nexus software artifactory as an active/passive implementation. Now for the Nexus VIP, since this is being controlled by the load balancer, you can setup the VIP as your point of entry for the Nexus servers that make up this active/passive implementation.
Nexus can handle the switch over, you just have to determine what you would be the best time frame to update the passive Nexus server via rsync (this could be 300 seconds or the value that you would consider important).
I would strongly recommend that you test your Nexus active/passive implementation prior to making this system part of your RA installation. Please make sure that you can switch over the active Nexus server to the passive via the VIP that you will be setting up.
Please let me know the outcome of your setup.
Thanks
-Walter